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The polarized optical emission (energy, intensity, lifetime) of the red modification of singlecrystal Pt(bpy)Cl 2  as a function of temperature (1.9 ≤ T ≤ 298 K) and homogeneous magnetic fields (0 ≤ H ≤ 6 T), and the temperature dependence of the polarized optical absorption are reported. Analysis of the spectra indicates a strong inter-complex coupling giving rise to electronic band structures and self-trapped states.

Luminescence of the Red Modification of Single-Crystal Pt(bpy)Cl 2 (bpy: 2,2′-Bipyridine): Evidence for Strong Inter-Complex Coupling