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Oxidation of 1,5-cyclooctadiene by SeO 2 /acetic anhydride (or SeO 2 /dioxane) yields the title compound 2a (or 2b, respectively). The type of reaction is not totally without precedent although the detailed mechanism is still unknown.

zeitschrift für naturforschung b

Notizen: 6-Acetoxy-9-selenabicyclo[3.3.1]-non-2-en: Unerwartetes Produkt der versuchten Se(IV)-Oxidation von 1,5-Cyclooctadien / 6-Acetoxy-9-selenabicyclo[3.3.1]-non-2-en: An Unexpected Product of the Se(IV)-Oxidation of 1,5-Cyclooctadien