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1:1-Electrolytes of the type [tris(dimethylamino)cyclopropendiylium] 2 +  ElX 6  2-  have been synthesized for the first time (El = Sn, Te; X = Cl, Br). Analysis of their UV spectra points to a novel OSCT-interaction within these ion pairs in which the complex anion acts as the donor. With 48-electron systems as SnX 6  2-  the bromo complex is the better donor than the chloro complex whereas with 50-electron systems TeX 6  2-  the reverse behaviour is observed. These contrasting tendencies can be explained by a simple MO model, according to which SnX 6  2-  anions interact with the organic acceptor via a HOMO of t lu-  symmetry, whereas anions of the type TeX 6  2-  employ their a lg *-HOMO.

zeitschrift für naturforschung b

Outer-sphere-CT-Wechselwirkungen zwischen einem organischen π-Radikaldikation und Hauptgruppenelement-Hexahalogenat-Komplexen / Outer-Sphere-CT-Interactions between an Organic π-Radical Dication and Main-Group Hexahalogenate Complexes