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The complex [C 5 Me 5 Ru(PMe 3 ) 2 (SO 2 )] +  is susceptible to nucleophilic attack at sulfur as shown by the reaction with ROH/Na 2 CO 3  (R = Me, Et, i-Pr) which gives the metallosulfonic esters [C 5 Me 5 Ru(PMe 3 ) 2 (SO 2 OR)].

zeitschrift für naturforschung b

Notizen: Nukleophile Addition von Alkoxid an einen kationischen Ruthenium-Schwefeldioxid-Komplex [1] / Nucleophilic Addition of Alkoxide to a Cationic Ruthenium Sulfur Dioxide Complex [1]