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The title compound 1 was obtained by the reaction of CuBr 2  and thiobenzamide in methanol. Its magnetic susceptibility and its EPR spectrum show it to be a Cu(II) compound. The two different ligands PhCSNH 2  (2) and [PhCSNH] -  (3) show up by distinct absorption bands in the IR spectrum. The crystal structure of 1 was determined by X-ray diffraction (1289 observed, unique reflexions, R = 0.048). Crystal data: monoclinic, space group P2 1 /n, Z = 2, a = 912.0(2), b = 1859.7(8), c = 1006.2(6) pm, β = 110.73(4)°. There are dimeric, centrosymmetric molecules in which the copper atoms are linked via the sulfur atoms of either 2 or 3, probably 3. The copper atoms show the coordination of a flattened tetrahedron.

Thiobenzamid-thiobenzimid-bromo-kupfer(II), [Cu(PhCSNH 2 )(PhCSNH)Br] 2 / Thiobenzamide-thiobenzimide-bromo-copper(II), [Cu(PhCSNH 2 )(PhCSNH)Br] 2