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S,S-Dimethylsulfoximinato-diphenyl-N-trimethylsilylphosphoranylidenamin (1) reacts in a molar ratio of 1:1 with TiCl 4 , CpTiCl 3 , (Cp = C 5 H 5 ), VOCl 3 , and Cp*TaCl 4  (Cp* = C 5 Me 5 ) to yield the 1:1 adduct 1 · TiCl 4  (2) and the substituted products Me 2 S(O) = NPPh 2  = N-TiCpCl2 (3), Me 2 S(O) = NPPh 2 =N-VOCl 2  (4) and Me 2 S(O) = NPPh 2  = N-TaCp*Cl 3  (5). The structures of 3, 4 and 5 show short metal-nitrogen bond lengths.

Neue Übergangsmetallkomplexe mit dem Liganden Me 2 S(O )=NPPh 2 =N— /New Transition Metal Complexes with the Ligand Me 2 S(O)=NPPh 2 =N —