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[MONCl 3  · NC - C 2 Cl 3 ] 2  has been prepared by the reaction of MONCl 3  with trichloromethyl isocyanidedichloride, CCl 3 NCCl 2  , in CH 2 Cl 2  suspension. The compound forms redbrown. mois-ture sensitive crystals, which were characterized by their IR spectrum as well as by a crystal structure determination (2482 independent observed reflexions, R = 0.048). Crystal data (-70 °C): Space group P2 1 /c, Z = 2, a = 674.2(2); b = 2128.2(11); c = 786.0(4) pm: β = 102.81(3)°. [MONCl 3  • NC-C 2 Cl 3 ] 2  forms centrosymmetric dimeric molecules via chloro bridges with Mo-Cl bond lengths of 240.7 and 276.0 pm. The longer MoCl bond of the MOCl 2 MO ring is caused by the trans influence of the nitride ligand; the MoN bond length of 167 pm corresponds with a triple bond. The 2,3,3-trichloroacrylnitrile ligand is bonded by its nitrogen atom with a bond length of Mo -N = 216 pm; the Mo-N≡C-C sequence is almost linear with a remarkable short C-C bond of 143.0 pm.

zeitschrift für naturforschung b

Molybdännitridtrichlorid-2,3,3-trichloracrylnitril, [MoNCI 3  · NC-C 2 Cl 3 ] 2  Synthese, IR-Spektrum und Kristallstruktur / Molybdenumnitridetrichloride-2,3,3-trichloroacrylnitrile, [MoNCl 3  · NC—C 2 Cl 3 ] 2  Synthesis, IR Spectrum, and Crystal Structure