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For the first time,  107,109 Ag ENDOR measurements in solution are reported. In addition, the formation of the known paramagnetic contact ion pair [Ag ⊕ (PR3) 2 (R 2 H 2 C 6 O 2  ·⊖ ] on reduction of 3,5-di(tert-butyl)-o-benzoquinone in THF solution containing soluble silver salts and triphenylphosphine is studied by cyclic voltammetry.

zeitschrift für naturforschung b

Elektronentransfer und Ionenpaar-Bildung, 8 [1]  107,109 Ag ENDOR-Kopplungen und Redox-Verhalten des Radikal-Kontaktionenpaares aus Bis(triphenyIphosphino)silber(I)-Kation und 3,5-Di(tert-butyl)-o-benzosemichinon-Anion / Electron Transfer and Ion Pairing, 8 [1]  107'109 Ag ENDOR Couplings and Redox Behaviour of the Radical Contact Ion Pair from Bis(triphenylphosphino)silver(I) Cation and 3,5-Di(tert-butyl)-o-benzosemiquinone Anion