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3 different modifications of TbCl 3  were synthesized. TbCl, (UCl 3 -type), probably in a metastable state, crystallizes in space group P6 3 /m with a = 737.63(2) pm, c = 405.71(2) pm and Z - 2. TbCl 3  (PuB 3 -type) crystallizes in space group Cmcm with a = 384.71(6) pm, b = 1177.37(7) pm. c = 851.77(4) pm and Z = 4. h-TbCl 3 , the high temperature phase being stable above 790 K. crystallizes in space group P4 2 /mnm with a = 642.51(4) pm, c = 1177.14(18) pm and Z = 4.

Zur Polymorphie von TbCI 3 / Polymorphism of TbCl 3