English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

[(F 3 CC 6 H 4 NNNC 6 H 4 CF 3 )Cu] 4  (1) and [(F 3 CC 6 H 4 NNNC 6 H 4 CF 3 )Ag] n  (2) are obtained by the addition of a solution of CuCl or AgNO, in CH 3 CN to a solution of Na(F 3 CC 6 H 4 NNNC 6 H 4 CF 3 ) in THF. Recrystallization of 1 in toluene/n-hexane yields air-stable orange crystals (tetragonal space group P4̄2 1 c, lattice constants a - 1527.7(5), c = 1281.3(4) pm, Z = 2). Complex 1 forms tetrameric units of symmetry S 4  with the four Cu atoms forming a slightly folded rhombus. The triazenido ligands bridge the Cu atoms alternatingly above and below the rhombic Cu 4  ring resulting in short Cu -Cu interactions of 257.9 pm. Complex 2 crystallizes from pyridine/methanol in form of yellow, air-stable crystals exhibiting a weak temperature independent paramagnetism of 0.64 B.M. per Ag atom at room temperature. The lattice constants are a = 2943(2), b = 475.8(5), c = 2280(1) pm. β = 111.99(6)°. Z = 8 for the monoclinic space group P2 1 /c. The Ag atoms form zigzag chains with short Ag-Ag distances of 283.4 and 284.0 pm and angles Ag-Ag-Ag of 113.7 and 114.1°. The bridging triazenide ligands are arranged alternatingly above and below the Ag-Ag chain. Two symmetry independent zigzag chains are found in the unit cell.

zeitschrift für naturforschung b

Synthese und Struktur von 1,3-Bis(4-trifluormethylphenyl)triazenido-Komplexen des Kupfer(I) und Silber(I) / Synthesis and Structure of 1,3-Bis(4-trifluormethylphenyl)triazenido Complexes of Copper(I) and Silver(I)