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The unit cell of TlBrI 2  (4-methylpyridine-N-oxide) 2 is orthorhombic, space group Pnna. with a = 1126.9(3),b = 919.8(2),c = 1210.4(3) pm.and Z = 4. The structure consists of discrete TlBrI 2  (4-methyl-pyridine-N-oxide) 2  molecules which have a distorted trigonal-bipyramidal geometry. The thallium atom is coordinated to two iodine atoms and a bromine atom in equatorial positions, and by two 4-methyl-pyridine-N-oxide ligands in the axial positions.

The Crystal Structure of TlBrI 2 (4-methylpyridine-N-oxide) 2