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1,5-Naphthalinediol yields with a secondary amine and formaldehyde under special conditions the mono Mannich base. Following hydrogenolysis with palladium charcoal results in 2-methyl- 1,5-naphthalinediol.

zeitschrift für naturforschung b

Modellreaktionen zur Plumbagin-Synthese, 1. Mitteilung Monoaminoalkylierung von 1,5-Naphthalindiol und anschließende Hydrogenolyse / Model Reactions for Plumbagin Synthesis, 1st Communication Monoaminoalkylation of 1,5-Naphthalinediol with Following Hydrogenolysis