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The isotypic compounds SrPt 4 P 6  , SrPt 4 As 6  and BaPt 4 As 6  were found to crystallize with a Pyrite-type derivative structure (monoclinic, C2/c, Z = 4) in which one Sr or Ba atom per formula unit occupies the position of a P 2  or As 2  pair. BaPt 2 P 3  forms another Pyrite-type related structure (monoclinic, P2 1 /c, Z = 4) built up by Ba 2 Pt and Pt 3 P 6  layers. All crystal structures were refined from four-circle diffractometer data, the lattice constants are:

zeitschrift für naturforschung b

Ternäre Varianten des Pyrit-Typs: Darstellung und Struktur von SrPt 4 P 6 , SrPt 4 As 6 , BaPt 4 As 6  und BaPt 2 P 3  / Ternary Pyrite-Type Derivatives: Preparation and Crystal Structure of SrPt 4 P 6 , SrPt 4 As 6 , BaPt 4 As 6  and BaPt 2 P 3