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A series of carbonyl metal complexes with anions of functional α-amino acids has been pre­pared: [M(CO) 3 (L-histidinate)] -  (M = Cr. Mo, W), M(CO) 3 (L-histidinate) (M = Mn, Re), [Re(CO) 3 (NO)(L-histidinate)] +  PF 6  - ,M(CO) 2 (η 3 -allyl)(L-histidinate) (M = Mo, W), Mo(CO) 2 (NO)(L-histidinate), [Mo(CO)(NO)(η 3 -methallyl)(L-histidinate)]PF 6 , Mo(CO) 2 (η 3 -methallyl)(L-histidineOMe)Cl, [M(CO) 3 ,(cysteinate)] 2-  (M = Mo. W), [Mo(CO) 3 (glyglyO)(H 2 O)] -  , [Re(CO) 3 (L-ornithinate)(CH 3 CN)] and [Re(CO) 3 (L-lysinate)]. The IR and NMR data of the new complexes are reported.

zeitschrift für naturforschung b

Metallkomplexe mit biologisch wichtigen Liganden, XLII [1].  Carbonylmetallkomplexe mit Anionen von mehrfunktionellen α-Aminosäuren / Metal Complexes with Biologically Important Ligands, XLII [1].Carbonyl Metal Complexes with Anions of Polyfunctional α-Amino Acids