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Hydroxyl radical reactions with trimethylamine in aqueous solution lead to the formation of the aminoalkyl radical (CH 3 ) 2 NCH 2  (A) and its conjugated acid (CH 3 ) 2 HN + CH 2  (AH + ) as well as to the alkylamine radical cation (CH 3 ) 3 N + (N + ). These radicals are transform ed into each other by hydrolytic reactions, e.g.

zeitschrift für naturforschung b

The Oxidation of Trimethylamine by OH Radicals in Aqueous Solution, as Studied by Pulse Radiolysis, ESR, and Product Analysis. The Reactions of the Alkylamine Radical Cation, the Aminoalkyl Radical, and the Protonated Aminoalkyl Radical