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Complexes of dihalophosphanes L n M-P(R)(Hal) 2  (L n M = 16-electron fragment e.g. Cp(CO) 2 Mn) undergo transformations into phosphinidene-, diphosphene- or diphosphanederivatives upon treatment with metallating agents (e.g.  t BuLi/TMEDA).

zeitschrift für naturforschung b

Halogen-Metall-Austausch an Dihalogenphosphan-Komplexen; Synthese von Diphosphan-, Diphosphen- und Phosphiniden-Derivaten / Halogen Metal Exchange; Diphosphane-, D iphosphene-, Phosphinidene-Complexes