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The first seleninylamine,  t BuNSeO, was prepared from tert-butylamine,  t BuNH 2 , and SeOCl 2  (3:1). The selenium diimide Se(NBu t ) 2  was isolated from the corresponding reaction of  t BuNH 2  and SeCl 4  (6:1); it decomposes at ambient temperature to give cyclic Se 3 (NBu t ) 2 . The new compounds were characterized on the basis of their IR ,  1 H and  13 C NMR and mass spectra.

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Neue Selen-Stickstoff-Verbindungen tert-Butyl-seleninylamin, Bu t NSeO, und Di(tert-butyl)selendiimid, Se(NBu t ) 2 /New Selenium-Nitrogen Compounds tert-Butyl-seleninylamine, Bu t NSeO, and Di(tert-butyl)selenium Diimide, Se(NBu t ) 2