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As a major product from the reaction of PNP-nitrite [P = P(C 6 H 5 ) 3 ] with elementary sulfur or a PNP-polysulfide (PNP) 2 S 12  in acetone under anaerobic conditions PNP-perthionitrite (PNPnitrosodisulfide) PNP-SSNO has been isolated. VIS/UV-spectra point to a thionitrate or perthionitrate as a precursor.

PNP-Perthionitrit und PNP-Monothionitrit / PNP-Perthionitrite and PNP-M onothionitrite