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Tricyclopentadienylneodymium and -lutetium react with sec-butyl lithium and terf-butyl lithium to form sec-butyl- and tert-butyl(dicyclopentadienyl)neodymium and -lutetium, which decompose to the corresponding dicyclopentadienyllanthanide hydride complexes. Dicyclopentadienyl-bis-(trimethylsilyl)methylsamarium and -lutetium are made from dicyclopentadienylsamarium or -lutetium chloride and bis(trimethylsilyl)methyl lithium. They react with hydrogen to form the corresponding dicyclopentadienyllanthanide hydride complexes.

zeitschrift für naturforschung b

Metallorganische Verbindungen der Lanthanoide, XXXIII [1] Dicyclopentadienyllanthanoid-alkyle und -hydride von Neodym, Samarium und Lutetium [2] / Organometallic Compounds of the Lanthanides, XXXIII [1] Dicyclopentadienyllanthanide Alkyls and Hydrides of Neodymium, Samarium and Lutetium [2]