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[2,3-Bis(diphenylphosphino)m aleicanhydride]- MCl 2  (M = Pd, Pt) reacts with M (PPh 3 ) 4  (M = Pd, Pt) to form paramagnetic, mononuclear complexes of Pd (Pt). It is shown by EPR , IR and X-ray examination, that the unpaired electron is delocalized on the bidentate phosphine ligand.

zeitschrift für naturforschung b

Notizen: Darstellung und Kristallstruktur einkerniger, paramagnetischer Pd- und Pt-Komplexe/ Preparation and Crystal Structure of Mononuclear, Paramagnetic Pd- and Pt-Complexes