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The crystal and molecular structure of Ph 2 Si(NMeBMe) 2 NMe (1) and MeB(NMeSiPh 2  ) 2 NMe (2) have been determined by X-ray structure analyses. Both compounds possess almost planar heterocycles. The average BN bond lengths in both compounds are practically identical (1.44 Å), but the two nonequivalent SiN bonds in 2 are significantly different (1.719, 1.732 Å). NMR data (  1 H,  11 B,  13 C,  27 Si) are consistent with planar silaborazine rings.

zeitschrift für naturforschung b

Beiträge zur Chemie des Bors, 163 [1]. Die Molekülstruktur zweier Silaborazine / Contributions to the Chemistry of Boron, 163 [1]. The Molecular Structure of Two Silaborazines