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16 compounds of the types cis-[Pt(PPh 3 ) 2 (4-CH 3 -C 6 H 4 )(Ar)] (cis-6a-g) and cis-[Pt(PPh 3 ) 2 (4-CH 3 O- C 6 H 4 )(Ar)] (cis-7a-g) (Ar = Phenyl ring substituted by at least one electron acceptor or donator substituent) have been synthesized and studied with respect to the thermal reductive elimination of the biphenyl system.

zeitschrift für naturforschung b

Synthesen und thermisches Verhalten von Verbindungen des Typs cis-(Phenyl)(phenyl′)bis(triphenylphosphan)platin(II) mit Substituenten unterschiedlichen Charakters in den platin-gebundenen Phenyl-Ringen / Syntheses and Therm al Behaviour of Compounds of the Type cis-(Phenyl)(phenyl′)bis(triphenylphosphane)platinum (II) with Substituents of Different Character in the Platinum -bound Phenyl Rings