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By reaction of a 1-unsubstituted imidazole (im H) with alkali and R 3 ′PAuCl under phase transfer conditions or in MeOH solution R 3 ′PAu (im-N) compounds were obtained where R′ = C 6 H 11  or t-Bu, and imH was imidazole, 2-i-Pr-, 4-NO 2 -imidazole or benzimidazole. When the Ph 3 Sb (or Ph 3 As) homologue was reacted, polymeric [μ-(2-methylimidazolato-N,N′)gold(I)] n  was obtained, together with (Ph 3 Sb) 2 AuCl.

Linear GoId(I) Derivatives with Bulky Phosphine and Imidazolato Ligands. X-Ray Crystal Structure of 1-(C 6 H 11 ) 3 PAu-2-i-Pr-Imidazole · C 6 H 6