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The ESCA -spectroscopic examination of λ 3 - and λ 5 -phosphorines supports the theory, that these compounds are to be described as aromatic compounds and as cyclic phosphonium-ylides, respectively. Contrary to simple electronegativity considerations, the phosphorus atom in the λ 3 - phosphorines is nearly neutral and not positively charged.

zeitschrift für naturforschung b

ESCA-Untersuchungen über die Ladungsverteilung und den Bindungszustand der λ 3 - und λ 5 -Phosphorine / ESCA-Studies of the Charge Distribution and Boding of λ 3 - and λ 5 -Phosphorines