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ReNCl 2 (PMe 2 Ph) 3  reacts as a Lewis base and with BCl 3  forms a nitrido bridge between Re and B. The resulting complex Re(NBCl 3 )Cl 2 (PMe 2 Ph) 3  crystallizes orthorhombic in the space group Pn2 1  a with Z = 4. In the complex each Re atom has six nearest neighbours in an almost octahedral arrangement with the NBCl 3  group being trans to one of the Cl ligands. The difference between the two Re-Cl bond lengths (239,4 and 243,9 pm) indicates a weak trans effect of NBCl 3 . The linear bridge Re≡N-B has bonding distances of Re-N = 172,8 and N-B = 153 pm. Bonding of BCl 3  by the nitrido ligand causes a small increase in the Re-N bond distance.

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Synthese und Kristallstruktur von Re(NBCl 3 )Cl 2 [P(CH 3 ) 2 C 6 H 5 ] 3 , ein Komplex mit einer Nitridobrücke zwischen Rhenium und Bor / Synthesis and Crystal Structure of Re(NBCl 3 )Cl 2 [P(CH 3 ) 2 C 6 H 5 ] 3 , a Complex with a Nitrido Bridge between Rhenium and Boron