English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

Trithiazyltrichloride reacts with osmium trichloride to give a green product of composition Os(NS)Cl 3  (1). Addition of [PPh 4 ]Cl to 1 in aqueous solution yields [PPh 4 ] 2 [Os(NS)Cl 5 ] (2) which is converted to [PPh 4 ][(H 2 O)Os(NS)CI 4 ] (3) by recrystallisation from a 1:1 water/methanol mixture. Crystals of 3 are monoclinic, space group P2 1 /c, with a = 1103.3(2), b = 1959.8(3), c = 1254.3(2) pm, β = 96.51(3)° and Z = 4. The structure was solved by automated Patterson interpretation and refined to R = 0.029 for 3177 unique observed diffractometer data. The osmium atom is octahedrally co-ordinated with H 2 O trans to the NS group. The Os-N-S unit is almost linear [174.9(3)°] with Os-N 173.1(4) and N-S 151.4(5) pm. The anions form dimeric units in the crystal, each held together by four O-H···Cl hydrogen bonds

Preparation and Structure of Tetraphenylphosphonium Aquotetrachlorothionitrosylosmium(II), [PPh 4 ][(H 2 O)Os(NS)Cl 4 ]