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The insertion of hexafluoroisopropylidenimine (1) into the P - H bonds of the phosphanes PH 3 , MePH 2  and Me 2 PH yields the (1,1,1-Trifluoro-2-amino-2-trifluoromethyl)ethylphospanes (2-4). Trimethylphosphane is oxidized to give the phosphine-imine Me 3 P = N-CH(CF 3 ) 2  (5).

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Reaktionen von Phosphanen Me n PH 3-n  (n = 0—3) mit Hexafluorisopropylidenimin / Reactions of the Phosphanes Me n PH 3-n  (n = 0—3) with Hexafluorisopropylidenimine