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The redox reactions between the iodogallanes Gal 3  as well as PhGaI 2  and the disulfides CH 3 SSCH 3  and PhSSPh lead to the monoalkylthio- and monoarylthiogallanes CH 3 SGaI 2  and PhSGaI 2  respectively. No reaction occurs between Inl 3  and these disulfides, whereas, surprisingly, Phlnl 2  does react to give the monoalkylthio- and monoarylthioindanes CH 3 SInI 2  and PhSInI 2 , respectively, Ph 2 GaI and Ph 2 InI form only the thioether adducts with the disulfides, which were not isolated. Initative mechanisms of these reactions are reported.

zeitschrift für naturforschung b

Über einige Redox-Reaktionen von Iodgallanen und lodindanen mit organischen Disulfiden / Some Redox Reactions of Iodogallanes and Iodoindanes with Organic Disulfides