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The preparation of S 4 N 5 F by fluoride ion addition to the S 4 N 5  + -cation in liquid SO 2  is described. The structure of the fluoride was determined from single crystal data. The mechanism for the formation of S 4 N 5 F and the stability of possible isomers is discussed on the basis of MNDO/1 calculations

Tetraschwefel-pentastickstoff-fluorid / Tetrasulfur-pentanitrogen Fluoride