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Reaction of tri-tert-butyl(dihalomethyl)silanes (halo = chloro, bromo) with organolithium compounds, by lithium/halogen or lithium/hydrogen exchange, leads to the corresponding carbenoids which by lithium halide elimination could give the carbenes (t-C 4 H 9 ) 3 SiCX. Further intermolecular or intramolecular reaction of these reactive intermediates provides a variety of crowded molecules including alkyltri-tert-butylsilanes, 1,2-bis(tri-tert-butylsilyl)- substituted ethanes and ethenes and ring substituted 1,2-di-tert-butyl-1-silacyclo-butanes. An X-ray structure determination of (E)-1,2-bis(tri-tert-butylsilyl)-1,2-dichloroethene reveals neither a twisting nor an elongation of the CC double bond, but the C = C-Si bond angles exhibit rather unusual values (up to 137.7°) and the Si-C (sp 2 ) bonds are as long as 195 pm.

zeitschrift für naturforschung b

Siliciumverbindungen mit starken intramolekularen sterischen Wechselwirkungen, XIV [1] Versuche zur Synthese des Tetra-tert-butylsilans: Tri-tert-butylisopropylsilan und verwandte Verbindungen / Silicon Compounds with Strong Intramolecular Steric Interactions, XIV [1] Attempted Synthesis of Tetra-tert-butylsilane: Tri-tert-butylisopropylsilane and Related Compounds