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The reaction of C 5 H 5 (CO) 2 Mn[C(C 6 H 5 )F] with n-C 4 H 9 Li results in cleavage of the C(carbene)-F bond and formation of C 5 H 5 (CO) 2 Mn[C(C 6 H 5 )n-C 4 H 9 ]. In a similar way fluoride can be abstracted by ethanol to yield C 5 H 5 (CO) 2 Mn[C(C 6 H 5 )OC 2 H 5 ].

zeitschrift für naturforschung b

Übergangsmetall-Carben-Komplexe, CXXX. Nucleophile Spaltung der Kohlenstoff-Fluor-Bindung in einem Fluorcarben-Komplex des Mangans/ Transition Metal Carbene Complexes, CXXX. Nucleophilic Cleavage of the Carbon-Fluorine Bond in a Fluorocarbene Complex of Manganese