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The new complexes K 2 [ML 2 ] (M = ═Mn, Cu), K 2 [ML 2 (H 2 O) 2 ] (M = Co, Ni), K 2 [Cu 2 L 2 (OH) 2 ] and K 2 [Cu 2 L 2 (OH) 2 (H 2 O) 4 ], where LH 2  = Bis(o-aminobenzenesulfonyl)ethylenediamine, have been prepared. Properties, X-ray powder patterns, molar conductance measurements, magnetic moments and spectral (IR, diffuse reflectance, visible in solution) data are discussed in terms of possible structural types and the nature of the bonding.

Deprotonated Complexes of Bis(o-aminobenzenesulfonyl)ethylenediamine with Mn(II), Co(II), Ni(II) and Cu(II)