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The photochemical reaction of a lithiated aminofluorosilane with Cr(CO) 6  leads to substitution of one or two carbonyl oxygen atoms and formation of isonitrile complexes. The crystal structure of the disubstituted product, cis-di(tert-butylisonitrile) tetracarbonylchromium, has been determined.

zeitschrift für naturforschung b

Angriff eines lithiierten Aminofluorsilans auf die C-O-Bindung des Cr(CO) 6 ; Bildung von Isonitrilkomplexen/Attack by a Lithiated Aminofluorosilane on the C - O Bond of Cr(CO) 6 ; Formation of Isonitrile Complexes