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Infrared spectra have been recorded of (CF 3 S) 2 CS in the gas and solid phase as well as isolated in noble gas matrix; the Raman spectra of the liquid have also been taken. The analyses of the spectra show that this compound consists of a complex mixture of conformers. By photolysis in a matrix with light of wavelength &gt; 300 nm the distribution of the conformers changes and with light of wavelength &gt; 530 nm this change can be reversed. The threshold for photochemical decomposition in the matrix is about 300 nm. The decomposition products consist of an equimolar mixture of CF 3 SCF 3  and CS 2 .

Photochemisches Verhalten von (CF 3 S) 2 CS in Inertgasmatrix/Photochemical Behavior of (CF 3 S) 2 CS in Rare Gas Matrix