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Intensely yellow coloured, insoluble gold(I)-bis(diarylphosphino)amides, [(C 6 H 5 )P 2 NAu, 1, is obtained from lithiated bis(diphenylphosphino)amine and AuCl complexes of tertiary phosphines. 1 is assigned a dimeric eightmembered ring structure on the basis of its  197 Au-Mößbauer spectrum and of a direct analogy with the corresponding bis(phosphino)methanide complexes, whose structure has recently been confirmed by X-ray diffraction.

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Gold(I)-Bis(diphenylphosphino)amid und einige Gold(I)-Bis(diarylphosphino)methanide mit sterisch anspruchsvollen Arylsubstituenten / Gold(I)-bis(diphenylphosphino)amide and Some Gold(I)-bis(diarylphosphino)methanides with Bulkyl Aryl Substituents