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The electrochemical reduction and oxidation of sulfurdiimines R 1 -NSN-R 2  (R 1,2  = C 6 H 5 , C 6 F 5 , C 6 H 5 S, C 6 F 5 S) in organic solvents is studied. Both reactions proceed in the sulfur-nitrogen system in a one-electron step. The influences of the substituents are, however, different.

zeitschrift für naturforschung b

Schwefel-Stickstoff-Verbindungen, XI. Elektrochemische Untersuchung einiger aromatisch substituierter Schwefeldiimide/ Sulfur-Nitrogen Compounds, XI. Electrochemical Investigations on Some Aromatic Substituted Sulfurdiimides