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Reactions of [Ir(COD)Cl] 2  (COD = 1,5-cyclooctadiene) with either i-C 3 H 7 MgBr or CH 3 Li in the presence of dimethyl-and diethylfulvene, respectively, yield complexes of the type [Ir(COD)(C 5 H 4 R)] where C 5 H 4 R is a cyclopentadienyl ligand. The nature of the substituent R depends on the fulvene as well as on the alkyl reagent. The compounds were characterized by NMR and mass spectra and in one case by X-ray diffraction analysis.

zeitschrift für naturforschung b

π-Olefin-Iridium-Komplexe, VII [1] Komplexbildung von Iridium mit Fulvenen / π-Oefin Iridium Complexes, VII [1] Complex Formation of Iridium with Fulvenes