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The molecular structure of the bridged [1]-titanocenophane 1,1'-dimethylsilylene titanocene dichloride, (CH 3 ) 2 Si(C 5 H 4 ) 2 TiCl 2 , has been investigated by an X-ray structure determination. Crystal data: monoclinic, space group C2/c, Z = 4, a = 1332.9(3), 6 = 988.7(3), c = 1068.9(3) pm, β = 113.43(2)°. The results are compared with the structural dimensions of similar compounds: 1,1'-methylene titanocene dichloride, CH 2 (C 5 H 4 )TiCl 2 , with the unbridged titanocene dichloride, (C 5 H 5 ) 2 TiCl 2  and the ethylene-bridged compound (CH 2 ) 2 (C 5 H 4 ) 2 TiCl 2

zeitschrift für naturforschung b

Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH 3 ) 2 Si(C 5 H 4 ) 2 TiCl 2  / Molecular and Crystal Structure of l,r-Dimethylsilylene Titanocene Dichloride, (CH 3 ) 2 Si(C 5 H 4 ) 2 TiCl 2