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One-dimensional Conductors, Linear Chain Structures (C9H7INO · C12H4N4) triclinic PT, a = 7.161(5) Å, b = 8.639(5) Å, c = 17.392(6) Å, α -64.96(4)°, β = 80.64(3)°, γ = 76.99(3)°, V = 1075.6 Å 3  , Z = 2, d c  = 1.47 Mgm -3 . The structure was refined to R - 0.114 for 2022 reflections. It consists of segregated diadic stacks of TCNQ and 4-oxo-iodoquinolinium ions. Inter-planar distances in the TCNQ stack are 3.09(1) Å and 3.32(1) Å; 3.37(1) Å and 3.55(1) Å in the quinolinium stack.

Crystal and Molecular Structure of 4-Oxo-6-iodoqwnolinium(OIQn)-2,2'- (2,5-cyclohexadiene-1,4-diylidene)- bispropanedinitrile (TCNQ)