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The cis and trans 2-alkylidene-5-methylcyclohexanones have been separated and distinguished. 2-Benzylidene-5-methylcyclohexanone was also prepared in both forms. The CD, ORD, UV and IR spectra are recorded and discussed. The NMR data include solvent and temperature effects.

Conformational Studies of R-(+)-2-Alkylidene-and R-(—)-2-Benzylidene-5-methylcyclohexanones