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Primary phosphanes, RPH 2 , react with carbonic ester chlorides, ClCOOR′, in the presence of K 2 C0 3  to yield the title compounds RPHCOOR′ and RP(COOR′) 2  . The NMR data of the novel compounds are presented and discussed. Other physical and some chemical properties are described.

Kohlensäureesterphosphide - Synthese und Reaktionsverhalten/ Carbonic Ester Phosphides - Synthesis and Chemical Behaviour