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Diels-Alder reactions between cyclopenta-diene and cis-crotonic acid derivatives were examined in the absorbed phase on various surfaces. The results indicate considerable differences under these conditions in the relative yields of exo and endo isomers. On silica gel, montigel, and aluminium oxide the reactions give mainly endo isomers.

zeitschrift für naturforschung b

Reaktionen von cis-Crotonsäurederivaten mit Cyclopentadien in heterogener Phase/ Reaction between cis-Crotonic Acid Derivatives and Cyclopentadiene in the Heterogeneous Phase