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In the course of our investigations of the ternary system Rb-Au-Sn we obtained the new compound Rb 4 Au 7 Sn 2 . Its crystal structure has been determined by single crystal X-ray diffraction data. It crystallizes in the hexagonal (rhombohedral) space group R3̄m with unit-cell parameters a = 680.1(3) pm and c = 2909.0(7) pm, and Z = 3. The structure is similar to that of Laves-Phases of the MgCu 2 -type.

Rb 4 Au 7 Sn 2 , eine intermetallische Phase mit siebenatomigen Goldclustern/ Rb 4 Au 7 Sn 2 , an Intermetallic Phase with Sevenatomic Gold-Clusters