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Dihydrazido thiophosphoric acid phenyl ester, (NH 2 NH) 2 P(= S)-OC 6 H 5  (DHTPPH), forms a 2:1 complex with manganese(II) chloride: [Mn(II)(DHTPPh) 2 Cl 2 ], soluble in methanol. Solvolysis yields the corresponding methyl ester complex. With water in methanol the dihydrazidothiophosphato complex [Mn(II){(NH 2 NH) 2 P(= O)S} 2 ] is formed. Monohydrazido thiophosphoric acid diphenyl ester NH2NH-P(= S)(OC 6 H 5 ) 2  (MHTPPh) gives various complexes with first row transition metals: [M(II)(MHTPPh) n X 2 ], n = 2, 4; X = halogen. The nickel complex (n = 4; X = Cl) is characterized by elemental analysis and spectroscopic methods. MHTPPh is monodentate through the terminal N atoms of the hydrazido groups. Iron(II) and cadmium complexes have different compositions (n- 2; X = Cl) and therefore different structures, probably with MHTPPh as a bidentate chelate ligand.

zeitschrift für naturforschung b

Komplexe zweifach positiver Übergangsmetallkationen mit Hydrazido-thiophosphorsäure-estern/ Complexes of Divalent Transition Metals with Hydrazido Thiophosphoric Acid Esters