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σ-C 3 H 5  · Mn(CO) 5  reacts with bis(diphenyl-phosphino)-N-methyl maleic anhydride to form a complex in which the C 3 H 5 -ligand migrates from the coordination sphere of Mn to the phosphine ligand. The high yield (70%) suggests that this reaction takes place within the coordination sphere of Mn. The product (X-ray analysis) shows unusual bonding properties.

zeitschrift für naturforschung b

Ungewöhnliche Substitutionsreaktion von (σ-Allyl)manganpentacarbonyl mit 2.3-Bis(diphenylphosphino)-N-methylmaleinimid / Unusual Reaction of (σ-Allyl)manganesepentacarbonyl with Bis(diphenylphosphino)-N-methyl Maleic Anhydride