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On irradiation of trans-di-tert-butylethylene at 185 nm in pentane the sterically congested cis-isomer was formed in ca. 40%. This π-π* excitation constitutes a convenient, direct method for the preparation of such usually difficult to prepare olefins

Direct Photochemical cis-trans Isomerization with 185 nm Radiation: A Facile Preparation of cis-Di-tert-butylethylene