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(η 3  -Allyl) (η 5  -cyclopentadienyl) palladium reacts with bis(diphenylphosphino)maleic an-hydride to form a complex in which the C 5 H 5  ligand is inserted into a P-C bond of the phos-phine ligand. The high yield (&gt;95%) suggests that this reaction takes place within the co-ordination sphere of palladium. The structure is studied by x-ray crystal structure analysis.

zeitschrift für naturforschung b

Zur Reaktion von (η 3 -Allyl)- (η 5 -cyclopentadienyl)palladium mit 2,3-Bis(diphenylphosphino)- maleinsäureanhydrid / Reaction of (η 3 -Altyl)(η 5 -cyclopentadienyl) Palladium with 2.3 - Bis (dipheny lphosphino) maleic Anhydride