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Cyanogen Halides The title compounds react with iodine to give the iodinecarbonyl complexes (η-C 5 H 5 )Co(CO)I 2  and (η-EtMe 4 C 5 )Co(CO)I 2 . The reactions of the same compounds with the cyanogen halides XCN (X = Br or I) give rise to the formation of mixed cyano-carbonyl complexes (η-C 5 H 5 )Co(CO)(CN)X and (η-EtMe 4 C 5 )Co(CO)(CN)X (X = Br or I) respectively. The compounds have been characterized by elemental analyses and IR and HNMR spectra.

Reactions of (η-C 5 H 5 )Co(CO) 2 and (η-EtMe 4 C 5 )Co(CO) 2 with Iodine and Cyanogen Halides, XCN (X = Br OR I)