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Crystals of the title compound are monoclinic (space group P2 1 /m) with a = 6.844(4) Å, 6 = 6.800(4) Å, c= 15.227(9) Å, y= 120.19° and Z = 2. The structure contains infinite cationic [(Te 12 O 22 )  4+ ]∞ -chains with three different sites for tellurium. There are three oxygen atoms in a y-tetrahedral arrangement around Te 1, and four oxygen atoms in a ψ-trigonal-bipyramidal coordination around Te 2 and Te 3.

Die Kristallstruktur von Te 6 O 11 Cl 2 / The Crystal Structure of Te 6 O 11 Cl 2