English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The reaction of [MoO 2 ((CH 3 )HN-O) 2 ] and N-methylhydroxylammoniumchloride in an aqueous suspension with CS 2  yields red crystals of the analytical composition MOC 4 H 14 N 3 O 4 S 2 . The crystal structure has been determined by single crystal X-ray diffraction analysis. The compound crystallizes in the monoclinic space group P2 1 /c, with cell constants a= 1333.2(3), b = 814.2(2), c = 2179.8(6) pm, β = 105.42(2)°, and Z = 8. The final R-value is 4.5% for 2965 unique reflexions. The structure consists of two crystallographically independent neutral complexes of molybdenum(VI). The geometry about the molybdenum is a distorted pentagonal bipyramid containing a terminal oxygen atom, two N-methylhydroxylamido(1-) ligands coordinated via the O-and N-atoms and an N-methyl-N-oxo-dithiocarbamato(2-) ligand forming a planar five membered ring with the molybdenum(VI) center (O,S-coordination).

zeitschrift für naturforschung b

Darstellung und Kristallstruktur von Bis-(N-Methylhydroxylamido(1-)-O.N)(N-methyl-N-oxo-dithiocarbamato-O.S)- oxo-molybdän(VI) / Synthesis and Crystal Structure of Bis(N-methylhydroxylamido(1-)-O,N)- (N-methyl-N-oxo-dithiocarbamato-O,S)-oxo-molybdenum(VI)